Monolayers on H-Si(111) were formed thermally
using decene and 10-bromodecene.
Samples were subjected to 100 percent
humidity in order to induce oxidation for
upwards of three weeks. The ability of
bromine to bind to the Si(111) and inhibit
oxidation through steric hindrance was
intended to be analyzed. Atomic force
microscopy...
In this study liquid-phase nanolithography
(LPN) techniques using conductive atomic
force microscopy are investigated in order
to study properties of nano-patterned
organic molecules covalently bound to a
silicon substrate. Previous work has shown
that LPN in the inert organic solvent hexadecane
forms patterned features on
hydrogen-passivated Si(111). Due to hexadecane’s...
In this study attention was focused on a
templated fabrication of Au nanotubular
structures that could carry a highly magnetic
entity such as cobalt. In brief, experimentation
was performed to create Co@Au
core-shell nanorods of different lengths. The
preliminary core-shell structures were first
characterized using x-ray diffraction (XRD),
scanning electron...
Chemical vapor deposition was used to
synthesize CdS nanowires via the vaporliquid-solid
growth mechanism. After Ti/Au
contacts were patterned to the nanowires
using electron beam lithography, photoresponse
studies were conducted. A significant
response was observed when the
wires were exposed to visible light; this
occurred as electrons in the nanowires...
This paper explores the various approaches
to time-resolved single nanoparticle spectroscopy.
Due to the novelty of these types
of experiments, several difficulties arise in
creating a feasible physical setup capable
of imaging single nanoparticles less than
100 nm in size. The various difficulties in
setup and their attempted resolutions will...
The optical properties of spherical gold
nanoparticles are calculated using classical
electrodynamics. The wavelength corresponding
to maximum extinction shifts to
longer wavelengths as the size of the
nanoparticle is increased. The influence of
higher-order multipoles is evident for large
nanoparticles, making the spectra more
complex. When the shell thickness of...
Every year millions of Americans go to the
emergency room with symptoms of a heart
attack. More than half a million Americans
die each year of myocardial infarctions (MI)
caused by coronary heart disease (CHD).
CHD detection is currently limited to EKG
analyses of electrical signals generated by
the heart...
Alzheimer’s disease (AD) is a progressive
mental disorder that affects 23 million people
worldwide. It is pathologically characterized
by amyloid plaques and tau tangles that
form in the brain. The hard, insoluble amyloid
plaques develop from the naturally
secreted amyloid beta peptide, which can
also assemble into toxic oligomeric forms...
Electron transfer theory predicts reorganization energy to be one factor that determines the electrochemical potential of a metal ion. This paper describes part of a study that aims to increase understanding of solvent reorganization energy in noncovalent systems by systematically varying the environment around a metal ion, specifically ruthenium. The...
An empirical procedure for fitting a complementary error function (erfc) to settlement and lateral ground movement data in a direction parallel to an excavation support wall is proposed based on extensive optical survey data obtained around a 12.8 m excavation in Chicago. The maximum ground movement and the height and...